Base Oils
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Group

Saturates(%wt)(ASTM D2007)  Sulfur(%wt) (ASTM D2622) Viscosity Index (ASTM D2270) Manufacturing method
I < 90 and/or> 0.03  80-120  Solvent refining
II >90 and <0.03  80-120 Hydroprocessing
III
>90 and <0.03
>120 Severe Hydroprocessing
IV
Polyalphaolefins(PAO)
  Chemical reaction
V
All other base stocks not included in Group I, II, III, IV or VI
   
VI Polyinternalolefins(PIO)   Chemical reaction

Group I

Group I base oils are classified as less than 90 percent saturates, greater than 0.03 percent sulfur and with a viscosity-index range of 80 to 120. Group I base oils are solvent-refined, which is a simpler refining process.
 
Group II
 
Group II base oils are defined as being more than 90 percent saturates, less than 0.03 percent sulfur and with a viscosity index of 80 to 120. They are often manufactured by hydrocracking, which is a more complex process than what is used for Group I base oils. Since all the hydrocarbon molecules of these oils are saturated, Group II base oils have better oxidation properties. They also have lower sulphur content and are lighter in color. Group II base oils are becoming very common on the market today.
 
Group III
 
Group III base oils are greater than 90 percent saturates, less than 0.03 percent sulfur and have a viscosity index above 120. These oils are refined even more than Group II base oils and generally are severely hydrocracked (higher pressure and heat). This longer process is designed to achieve a purer base oil. Although made from crude oil, Group III base oils are sometimes described as synthesized hydrocarbons. Like Group II base oils, these oils are also becoming more prevalent.
 
Group IV
 
Group IV base oils are polyalphaolefins (PAOs). These synthetic base oils are made through a process called synthesizing. They have a much broader temperature range and are great for use in extreme cold conditions and high heat applications.
 
Group V
 
Group V base oils are classified as all other base oils, including silicone, phosphate ester, polyalkylene glycol (PAG), polyolester, biolubes, etc. These base oils are at times mixed with other base stocks to enhance the oil’s properties. An example would be a PAO-based compressor oil that is mixed with a polyolester. Esters are common Group V base oils used in different lubricant formulations to improve the properties of the existing base oil. Ester oils can take more abuse at higher temperatures and will provide superior detergency compared to a PAO synthetic base oil, which in turn increases the hours of use.

 

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